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About Electroless Nickel Plating
Electroless nickel plating is a process in which a
coating of a nickel alloy (most commonly nickel-phosphorus) is deposited
onto a metallic substrate. This is a procedure that uses heat, which
is directly linked to the chemical reduction of nickel compounds. Unlike
electrolytic coatings, electroless nickel plating is performed without
the use of electricity. Electroless nickel plating also has better corrosion
resistance compared to other coating techniques. Any substrate surface
to which the coating solution has free access is capable of being coated
or plated.
Electroless nickel plating was first reported in 1946 by its accredited
discoverers, Grace Riddell and Abner Brenner. Nowadays, technology and
education have enabled the advancement of the nickel plating process.
Electroless plating is superior to electrolytic plating in its ability
to coat uniformly. There is also less excessive buildup on projections
and corners. Because of its benefits, electroless nickel plating is a
favorite for coating irregular objects that other processes have difficulty
covering. Products that have already been coated with electroless nickel
can undergo heat treatment in order to precipitate phosphorous from the
alloy, which increases hardness up to four times.
Various nickel deposits are available based mainly on the phosphorus
concentration. Low phosphorus deposits (1-4%) have the ability to be
welded or brazed, and are very corrosion resistant. For applications
where lubricity and heat tolerance are desired, a medium phosphorus concentration
(5-9%) is more beneficial. Maximum corrosion resistance for nickel plating
comes with a higher phosphorus concentration (10-15%). High amounts of
phosphorus add to the deposit’s non-magnetic and excellent ductile
qualities. Another property of phosphorous electroless nickel that makes
it highly beneficial is its ability to adhere to most metals.
Some examples of industries that use electroless nickel plating include
the petroleum, medical, dental, oil, gas, aerospace and automotive fields.
After choosing the deposit best suited for a particular application,
the thickness of the coating should be considered. Coating thicknesses
for electroless nickel plating range from less than .0005 inches to over
.01 inches. Thicker coatings often mean better corrosion resistance and
better wear characteristics. This provided, finding a quality finisher
is crucial in receiving a quality product. With all the advancements
in electroless nickel plating, it is surprising that the exact mechanism
for the deposition remains unknown, due to its complexity.
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Types of Electroless Nickel Plating
- is a finishing treatment that can be either bright chrome or hard chrome.
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use hard particulate matter mixed with electroless nickel plating chemicals.
Silicon carbides and synthetic diamonds are common types of composite
materials.
- creates a slick, low friction surface.
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is an alternate type of the coating/plating process. Using a low voltage
current, charged nickel compounds are attracted to a substrate’s
oppositely-charged surface; in this fashion, nickel deposits are transferred
through a solution and onto the substrate.
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has the best corrosion resistance of any electroless nickel plating
process. It is used in harsh environments, such as oil drilling and
coal mining.
- yields very good resistance to alkaline corrosive environments.
It also provides uniform thickness, so that grinding after the procedure
is unnecessary.
- is a popular form of nickel plating
that has been used over the years. It generates a nice uniform coating
and will not build up on the edges of the substrate.
- improve a product’s corrosion and wear resistance.
- is the process of depositing a metal or metal alloy onto a surface.
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are admired for their as-plated hardness, which is greater than that
of nickel-phosphorus platings. The melting point for N-B alloys is higher
than that of N-P, but chemical costs for nickel-boron baths can be up
to 10 times that of the nickel-phosphorus chemicals.
- is the process of coating an item with a nickel alloy to prevent oxidation.
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consist of nickel and boron or phosphorus. Other materials, such as
iron, cobalt and tungsten, are also included in poly alloys. Polly alloy
coatings allow maximum corrosion and high-temperature resistance, hardness
and magnetic or nonmagnetic qualities.
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